First use uLaunch to move the programs from your usb stick to your memory card, or you can leave them on if you want to use them from the usb stick.
Now run Free Mcboot Configurator and click on Configure OSDSYS Options then go to Configure Item and press right until you find an unused number and click on it, now click on Name: and type a name for the program, then click on Path1: and choose the program on MC0 or Mass depending on which one you want to use. If you want it to work when the memory card is in either slot you can move the memory card to slot two and choose the program on MC1 for Path2.
Do the same for all the programs you want then go back to the main screen and click Save CNF to MC0, then click Ps2 Browser (FMCB restart). Now the programs will be on your menu.